Gold catalysed synthesis of 3-alkoxyfurans at room temperature.

نویسندگان

  • Matthew N Pennell
  • Robert W Foster
  • Peter G Turner
  • Helen C Hailes
  • Christopher J Tame
  • Tom D Sheppard
چکیده

Synthetically important 3-alkoxyfurans can be prepared efficiently via treatment of acetal-containing propargylic alcohols (obtained from the addition of 3,3-diethoxypropyne to aldehydes) with 2 mol% gold catalyst in an alcohol solvent at room temperature. The resulting furans show useful reactivity in a variety of subsequent transformations.

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عنوان ژورنال:
  • Chemical communications

دوره 50 11  شماره 

صفحات  -

تاریخ انتشار 2014